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41.
LA‐ICP‐MS is increasingly applied to obtain quantitative multi‐element data with minimal sample preparation, usually achieved by calibration using reference materials (RMs). However, some ubiquitous RMs, for example the NIST SRM 61× series glasses, suffer from reported value uncertainties for certain elements. Moreover, no long‐term data set of analyses conducted over a range of ablation and tuning conditions exists. Thus, there has been little rigorous examination of the extent to which offsets between measured and reported values are the result of error in these values rather than analytically induced fractionation. We present new software (‘LA‐MINE’), capable of extracting LA‐ICP‐MS data with no user input, and apply this to our system, yielding over 5 years of data (~ 5700 analyses of ten glass and carbonate RMs). We examine the relative importance of systematic analytical bias and possible error in reported values through a mass‐specific breakdown of fourteen of the most commonly determined elements. Furthermore, these data, obtained under a wide range of different ablation conditions, enable specific recommendations of how data quality may be improved, for example the role of diatomic gas, the effect of differential inter‐glass fractionation factors and choice of transport tubing material. Finally, these data demonstrate that the two‐volume Laurin ablation cell is characterised by no discernible spatial heterogeneity in measured trace element ratios.  相似文献   
42.
  Songhui  Chao  Aimin  Liang  Qianyan  Cen  Jingyi  Wang  Jianyan  Jiang  Tao  Li  Si 《中国海洋湖沼学报》2022,40(6):2146-2163
Journal of Oceanology and Limnology - The naked dinoflagellate Takayama acrotrocha was identified as responsible for a bloom in Shenzhen Bay, Guangdong, China, in early spring 2021. The...  相似文献   
43.
基于永定河流域1958~2018年14个气象站的逐日观测数据,采用气候倾向率、Mann–Kendall趋势检验法分析蒸发皿蒸发量时空变化特征,并通过完全相关系数和多元回归分析识别气候因子与蒸发量的相关程度并定量计算其贡献率。结果表明:在全球气候变暖的背景下,60年来永定河流域气温以0.29°C/10 a的速率上升,而蒸发皿蒸发量不增反减,以-48.88 mm/10 a的速率显著下降(标准化统计量Z=-4.5),该流域存在明显的“蒸发悖论”现象。流域蒸发量表现出显著的时空分布差异性,在季节上,春、夏季蒸发量分别占全年蒸发量的35%和37%,且春、夏两季蒸发量下降趋势较为显著;在空间上,永定河流域下游平原区下降趋势较上游山区(天镇、蔚县等地区)更为显著。完全相关分析表明,净辐射、平均风速和空气饱和差与蒸发量具有较强的相关性;贡献率分析表明,与基准期 1958~1979 年相比,1980~2018 年平均风速和净辐射减少对蒸发量减少的贡献率分别为77%和66%,空气饱和差的贡献率为-41%,净辐射和平均风速的减少是导致蒸发皿蒸发量下降的主要影响因素。  相似文献   
44.
针对北京南郊观象台的Ka波段毫米波雷达以及L波段探空设备的观测原理和特点,提出了适用于各设备的云垂直结构判定方法,并基于二者2016年12月13日至2017年3月13日长达91 d的时空同步观测数据,结合激光云高仪、葵花8卫星、全天空成像仪等多源辅助数据,对探空与毫米波雷达观测结果(包括云底高、云顶高、云层数等)进行了对比,并对云高偏差的原因进行了分析,结论如下:毫米波雷达与探空判定的云垂直结构普遍具有较好的一致性,统计时段探空观测云顶高度比毫米波雷达平均高422 m,而云底高度则平均偏低350.7 m,导致二者观测云高差异主要包括二者观测原理不同、探空仪湿延迟、气球漂移引起的时空匹配偏差、探空判识云高算法的局限性、降雨时毫米波雷达的衰减等多方面。  相似文献   
45.
为了理解行星反照率时空变化规律及成因,基于CERES数据对全球行星反照率的大气(主要为云与气溶胶等)和地表贡献进行了分解,通过Theil-Sen+Mann-Kendall方法得到了2001~2018年全球行星反照率及其大气和地表贡献的时空变化趋势,并基于回归分析方法对典型区域的变化趋势进行了初步解释。研究结果表明:1)在中低纬度区域行星反照率的大气贡献占主导地位,而在高纬度区域地表贡献相对升高,呈现纬向差异大于经向变化的模式;2)全球行星反照率呈现?0.0002/a(p<0.05)的变化趋势,地表贡献和大气贡献呈现?0.00015/a(p<0.05)与–0.00004/a(p<0.05)的变化趋势;3)大气贡献在火地岛西南洋面等区域呈现显著的增长趋势,而在南极洲东部等区域呈现显著的降低趋势;地表贡献在北冰洋等区域呈现显著的降低趋势,而在南极洲东部等区域呈现显著的升高趋势,并且可以基于云覆盖、积雪覆盖和NDVI等参量的变化有效解释典型区域的行星反照率变化。  相似文献   
46.
Widespread magmatic activity developed in the Middle Miocene in the Cappadocian Region of Central Anatolia in Turkey. Despite several previous studies that focus on the geochemical features of the magmatic rocks, the source components and development of melting conditions are still a matter of debate.Recent basaltic rocks from Karaburna and Gül?ehir (1228 and 96 Ka, respectively, Dogan, 2011) are considered as a part of the Central Anatolian Volcanic Province, situated at the northernmost end of the Cappadocian Region. These lavas have similar large ion lithophile (LIL) (except Rb) and high field strength (HFS) element abundances, however, Karaburna samples are more enriched in HFS elements, and both of the rocks suites reflect HFS depletions relative to the OIB signature.Karaburna and Gül?ehir basalts have low Nb/La (0.45–0.5; 0.35–0.5), Nb/Th (2.75–4.61; 1.26–2.85) values, respectively, suggesting contributions from crustal sources, whereas Zr/Ba ratios of these samples range between 0.32–0.93 and 0.4–0.88 and imply that these rocks appear to be derived from asthenospheric sources. These incompatible element ratios can be attributed to either different geochemical processes, or are related to melting from different source component(s).The ambient mantle source of the Cappadocian region appears to be consistent with spinel peridotite, but this domain is not solely satisfactory to represent the melting conditions in the light of new elemental data. Values of Tb/Yb(N) and Zn/Fe provide new constraints suggesting the magmas were generated from the asthenosphere. Tb/Yb(N) ratio separates garnet – spinel transition Tb/Yb(N) (>1.8) and Zn/Fe ratio displays separation between the peridotite-derived (Zn/Fe <12) and pyroxenite-derived (13?20) melts.A melting model based on REE ratios and Zn/Fe, Co/Fe, Tb/Yb(N) values indicates that basaltic rocks were not derived from a single source component (peridotite). Instead, those values suggest substantial melting contributions from a pyroxenite source domain, which has not been discussed as a source component in previous studies. Melts, from both of the source domains, with the result of asthenospheric upwelling linked to the downgoing Aegean and Cyprean slabs, are distinct from the alkaline character frequently observed as the final products of recent volcanic activity in the Cappadocian region and also explains the different trace element variations observed in such a small scale.  相似文献   
47.
Onuşluel Gül  Gülay  Gül  Ali  Najar  Mohamed 《Natural Hazards》2022,110(2):1389-1404

In the context of major outcomes of a steadily changing climate, extreme climatic conditions and the associated events in various forms of weather-related natural disasters, e.g. droughts, floods, and heat waves, are more frequently experienced on the global scale in recent years. In support of this argument, there are adequate numbers of explicit signals over such a persistent outlook, which is greatly illustrated by historical data and observations. This study, which is mainly oriented to investigating the drought behaviour in Thracian, Aegean and Mediterranean transects of Turkey's major river basins, is actually inspired by the foreseen potential of using annual maximum drought severity series (based on drought definition through the standardized precipitation index (SPI)) within a framework that resembles the use of flood discharge directly from flow measurements in a river basin. To this end, a series of spatial analyses were employed to identify different aspects of flood appearance in the study extent, including trend views on annual average drought severity series, shifts in the starting time of the annually most severe flood periods, and changes in spatial coverage views of average drought conditions under different drought severity categories. The framework of the analytical approaches depends greatly on validated international datasets and open-source computational algorithms. The results from the analyses that were conducted in two consecutive periods of 1958–1980 and 1981–2004 revealed that Turkey's western and southern river basin systems seemed to have experienced quite different behaviours between the two periods in terms of drought severity magnitudes, drought durations and annual occurrence times.

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48.

The Genç District is located on the Bingöl Seismic Gap (BSG) of the Eastern Anatolian Fault Zone (EAFZ) with its?~?34.000 residents. The Karl?ova Triple Junction, where the EAFZ, the North Anatolian Fault Zone, and the Varto Fault Zone meet, is only 80 km NE of the Genç District. To make an earthquake disaster damage prediction of the Genç District, carrying a high risk of disaster, we have (1) prepared a new geological map, and (2) conducted a single-station microtremor survey. We defined that three SW-NE trending active faults of the sinistral Genç Fault Zone are cutting through the District. We have obtained dominant period (T) as?<?0.2 s, the amplification factor (A) between 8 and 10, the average shear wave velocity for the first 30 m (Vs30) as?<?300 m/s, and the seismic vulnerability index (Kg) as?>?20, in the central part of the Genç District. We have also prepared damage prediction maps for three bedrock acceleration values (0.25, 0.50, 0.75 g). Our earthquake damage prediction scenarios evidenced that as the bedrock acceleration values increase, the area of soil plastic behavior expands linearly. Here we report that if the average expected peak ground acceleration value (0.55–0.625 g) is exceeded during an earthquake, significant damage would be inevitable for the central part of the Genç District where most of the schools, mosques, public buildings, and hospitals are settled-down.

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49.
Tanyaş  Hakan  Görüm  Tolga  Fadel  Islam  Yıldırım  Cengiz  Lombardo  Luigi 《Landslides》2022,19(6):1405-1420

On November 14, 2016, the northeastern South Island of New Zealand was hit by the magnitude Mw 7.8 Kaikōura earthquake, which is characterized by the most complex rupturing mechanism ever recorded. The widespread landslides triggered by the earthquake make this event a great case study to revisit our current knowledge of earthquake-triggered landslides in terms of factors controlling the spatial distribution of landslides and the rapid assessment of geographic areas affected by widespread landsliding. Although the spatial and size distributions of landslides have already been investigated in the literature, a polygon-based co-seismic landslide inventory with landslide size information is still not available as of June 2021. To address this issue and leverage this large landslide event, we mapped 14,233 landslides over a total area of approximately 14,000 km2. We also identified 101 landslide dams and shared them all via an open-access repository. We examined the spatial distribution of co-seismic landslides in relation to lithologic units and seismic and morphometric characteristics. We analyzed the size statistics of these landslides in a comparative manner, by using the five largest co-seismic landslide inventories ever mapped (i.e., Chi-Chi, Denali, Wenchuan, Haiti, and Gorkha). We compared our inventory with respect to these five ones to answer the question of whether the landslides triggered by the 2016 Kaikōura earthquake are less numerous and/or share size characteristics similar to those of other strong co-seismic landslide events. Our findings show that the spatial distribution of the Kaikōura landslide event is not significantly different from those belonging to other extreme landslide events, but the average landslide size generated by the Kaikōura earthquake is relatively larger compared to some other large earthquakes (i.e., Wenchuan and Gorkha).

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50.
Gropius  M.  Dahabiyeh  M.  Al Hyari  M.  Brückner  F.  Lindenmaier  F.  Vassolo  S. 《Hydrogeology Journal》2022,30(6):1769-1787

Jordan suffers from water scarcity and groundwater covers the majority of Jordan’s water supply. Therefore, there is an urgent need to manage this resource conscientiously. A regional numerical groundwater flow model, developed as part of a decision support system for the country of Jordan, allows for quantification of the overexploitation of groundwater resources and enables determination of the extent of unrecorded agricultural groundwater abstraction. Groundwater in Jordan is abstracted from three main aquifers partly separated by aquitards. With updated geological, structural, and hydrogeological data available in the country, a regional numerical groundwater flow model for the whole of Jordan and the southernmost part of Syria was developed using MODFLOW. It was first calibrated for a steady-state condition using data from the 1960s, when groundwater abstraction was negligible. After transient calibration using groundwater level measurements from all aquifers, model results reproduce the large groundwater-level declines experienced in the last decades, which have led to the drying out of numerous springs. They show a reversal of groundwater flow directions in some regions, due to over-abstraction, and demonstrate that documented abstractions are not sufficient to cause the observed groundwater-level decline. Only after considering irrigation water demand derived from remote sensing data, the model is able to simulate these declines. Illegal abstractions can be quantified and predictive scenarios show the potential impact of different management strategies on future groundwater resources.

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